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The Alps in the age of the Anthropocene: the impact of human activities on the cryosphere recorded in the Colle Gnifetti glacier

  • Anthropocene - Natural and man-made alterations of the Earth
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Abstract

The evaluation of the impact of anthropogenic activities on mountain areas is an important task, because they represent the last remaining natural and pristine environments in highly industrialized continental regions. The deposition of ubiquitous, persistent and toxic organic pollutants in high-altitude sites can potentially affect the alpine ecosystem, which is often characterized by unique plant and animal communities which are precious in terms of ecological value as well as being fragile and easily spoiled. Records from Alpine ice cores have demonstrated to be among the best tools in paleoenvironmental studies to reconstruct past emissions of heavy metals and persistent organic pollutants. From the comparison of trace species records in the snow and ice with the emission inventories compiled in recent years it is also possible to reconstruct the past trends in the emission of these compounds. This knowledge enables a better environmental management and a more effective planning of the human activities in the light of a new sustainable development and could represent the base of a wide and motivated participation to the creation of the future generations. Here, we summarize the results of the geochemical analysis of the Colle Gnifetti firn/ice core, in the Monte Rosa group (NW European Alps).

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References

  • Baggoura B, Noureddine A, Benkrid M (1998) Level of natural and artificial radioactivity in Algeria. Appl Radiat Isot 49:867–873

    Article  CAS  Google Scholar 

  • Barbante C, Bellomi T, Mezzadri G, Cescon P, Scarponi G, Morel C, Jay S, Van De Velde K, Ferrari C, Boutron C (1997) Direct determinations of heavy metals at picogram per gram levels in Greenland and Antarctic snow by double focusing inductively coupled plasma mass spectroscopy. J Anal At Spectrom 12:925–931

    Article  CAS  Google Scholar 

  • Barbante C, Schwikowski M, Döring T, Gäggeler H, Schotterer U, Tobler L, Van De Velde K, Ferrari C, Cozzi G, Turetta C, Rosman K, Bolshov M, Capodoglio G, Cescon P, Boutron C (2004) Historical record of European heavy metals to the Atmosphere since the 1650s from Alpine Snow/Ice cores drilled near Monte Rosa. Environ Sci Technol 38(15):4085–4090

    Article  CAS  Google Scholar 

  • Böhm R, Auer I, Brunetti M, Maugeri M, Nanni T, Schöner W (2001) Regional Temperature Variability in the European Alps 1760–1998 from homogenised instrumental time series. Int J Climatol 21:1779–1801

    Article  Google Scholar 

  • Brännvall ML, Bindler R, Emteryd O, Renberg I (2001) Four thousand years of atmospheric lead pollution in northern Europe: a summary from Swedish lake sediments. J Paleolimnol 25:421–435

    Article  Google Scholar 

  • Brecciaroli TL(1995) La Bessa. Indagine nell’area della miniera d’oro romana. Quaderni della Sovraintendenza Archeologica del Piemonte 14:228–232

  • Budzinski H, Jones I, Bellocq J, Pierard C, Garrigues P (1997) Evaluation of sediment contamination by polycyclic aromatic hydrocarbons in the Gironde estuary. Mar Chem 58:85–97

    Article  CAS  Google Scholar 

  • Candelone JP, Hong S, Boutron CF (1994) An improved method for decontaminating polar snow or ice cores for heavy metal analysis. Anal Chim Acta 299(9):9–16

    Article  CAS  Google Scholar 

  • Carter MW, Moghissi AA (1977) Three decades of nuclear testing. Health Phys 33:55–71

    Article  CAS  Google Scholar 

  • Clavin P (2000) Great depression in Europe, 1929–1939. St. Martin Press, New York

  • Dansgaard W, Johnsen S, Moller J, Langway CC Jr (1969) One thousand centuries of climatic record from Camp Century on the Greenland ice sheet. Science 166:377–381

    Article  CAS  Google Scholar 

  • Dansgaard W, Johnsen S, Clausen HB, Gunderstrup HG (1973) Stable isotope glaciology. Medd Groenland 197:1–53

    Google Scholar 

  • DICoD (2007) Dossier de présentation des essais nucléaires et leur suivi au Sahara. Délégation à l’Information et à la Communication de la Défense, Paris (France)

  • Döscher A, Gäggeler HW, Schotterer U, Schwikowski M (1995) A 130 year deposition record of sulphate, nitrate and chloride from a high-alpine glacier. Water Air Soil Pollut 85(2):603–609

    Article  Google Scholar 

  • Eichler A, Schwikowski M, Gäggeler HW (2000) An alpine ice core record of anthropogenic HF and HCl emissions. Geophys Res Lett 27(19):3225–3228

    Article  CAS  Google Scholar 

  • EPA (2009) Priority Pollutants. http://www.epa.gov/waterscience/methods/pollutants.htm. Accessed 21 Oct 2013

  • Facchetti S, Geiss F, Gaglione P, Colombo A, Garibaldi G, Spallanzani G, Gille G (1982) Isotopic lead experiment: status report. Commission of the European Communities EUR8352 EN, Brussels

  • Favez O, Cachier H, Sciare J, Sarda-Esteve R, Martinon L (2009) Evidence for a significant contribution of wood burning aerosols to PM2.5 during the winter season in Paris, France. Atmos Environ 43:3640–3644

    Article  CAS  Google Scholar 

  • Fernandez P, Vilanova RM, Martinez C, Appleby P, Grimalt JO (2000) The historical record of atmospheric pyrolytic pollution over Europe registered in the sedimentary PAH from remote mountain lakes. Environ Sci Technol 34:1906–1913

    Article  CAS  Google Scholar 

  • Gabrieli J, Decet F, Luchetta A, Valt M, Pastore P, Barbante C (2010a) Occurrence of Polycyclic Aromatic Hydrocarbons in the seasonal snowpack of the Eastern Italian Alps. Environ Pollut 158:3130–3137

    Article  CAS  Google Scholar 

  • Gabrieli J, Vallelonga P, Cozzi G, Gabrielli P, Gambaro A, Decet F, Schwikowski M, Sigl M, Gaggler HW, Boutron C, Cescon P, Barbante C (2010b) Post 17th-century changes of European PAHs emissions recorded in high-altitude Alpine snow and ice. Environ Sci Technol 44:3260–3266

    Article  CAS  Google Scholar 

  • Gabrieli J, Carturan L, Gabrielli P, Kehrwald N, Turretta C, Cozzi G, Spolaor A, Dinale R, Staffler H, Seppi R, Dalla Fontana G, Thompson L, Barbante C (2011a) Impact of Po Valley emissions on the highest glacier of the Eastern European Alps. Atmos Chem Phys 11:8087–8102

    Article  CAS  Google Scholar 

  • Gabrieli J, Cozzi G, Schwikowski M, Sigl M, Gaggler HW, Boutron C, Barbante C (2011b) The history of nuclear testing recorded in an ice core from Colle Gnifetti, Swiss/Italian Alps. Atmos Environ 45:587–593

    Article  CAS  Google Scholar 

  • Gabrielli P, Planchon FAM, Hong S, Lee KH, Do Hur S, Barbante C, Ferrari C, Petit JR, Lipenkov VY, Cescon P, Boutron C (2006) Trace elements in Vostok Antarctic ice during the last four climatic cycles. Earth Planet Sci Lett 234:249–259

    Article  Google Scholar 

  • Giacosa P (1896) Indagini sulle acque e sulle nevi delle alte regioni. Bollettino del Club Alpino Italiano 1:45–64

    Google Scholar 

  • Hansen LB, Langway CC (1966) Deep core drilling in ice and core analysis at Camp Century, Greenland, 1961–1966. CRREL Spec. Report 126 n. 5

  • Harley JH (1980) Plutonium in the environment—a review. J Radiat Res 21:83–104

    Article  CAS  Google Scholar 

  • Havlovic V (1961) Deposition of fission product nuclides after two Sahara nuclear test explosions. Nature 189:977–978

    Article  CAS  Google Scholar 

  • Hong S, Candelone JP, Patterson CC, Boutron CF (1994) Greenland ice evidence of hemispheric lead pollution two millennia ago by Greek and Roman civilization. Science 265:1841–1843

    Article  CAS  Google Scholar 

  • Hong S, Candelone JP, Patterson CC, Boutron CF (1996) History of ancient copper smelting pollution during Roman and medieval times recorded in Greenland ice. Science 272:246–249

    Article  CAS  Google Scholar 

  • Huber TH, Schwikowski M, Gäggeler HW (2001) Continuous melting and ion chromatographic analyses of ice cores. J Chromatogr A 920:193–200

    Article  CAS  Google Scholar 

  • IAEA (2005) Radiological Conditions at the Former French Nuclear Test Sites in Algeria: Preliminary Assessment and Recommendations. International Atomic Energy Agency (IAEA), Radiological Assessment Reports Series, Vienna (Austria)

  • Kaufmann PR, Federer U, Hutterli MA, Bigler M, Schupbach S, Ruth U, Schmitt J, Stocker TF (2008) An improved continuous flow analysis system for high resolution field measurements on ice cores. Environ Sci Technol 42(21):8044–8050

    Article  CAS  Google Scholar 

  • Khalili NR, Scheff PA, Holsen TM (1995) PAH source fingerprintings for coke ovens, diesel and gasoline engines, highway tunnels and wood combustion emissions. Atmos Environ 29:533–542

    Article  CAS  Google Scholar 

  • League of Nations (1938) Statistical year-book 1937/38. League of Nations Publications, Geneva

    Google Scholar 

  • Lugauer M, Baltensperger M, Furger M, Gaggler HW, Jost DT, Schwikowski M, Wanner H (1997) Aerosol transport to the high Alpine sites Jungfraujoch (3454 m a.s.l.) and Colle Gnifetti (4452 m a.s.l.). Tellus Ser B Chem Phys Meteorol 50B:76–92

    Google Scholar 

  • Maupetit F, Delmas RJ (1994) Snow chemistry of high altitude glaciers in the French Alps. Tellus 46B:304–324

    Article  CAS  Google Scholar 

  • McConnel JR, Edwards R, Kok G, Flanner M, Zender C, Saltzman E, Banta R, Pasteris D, Carter M, Kahl J (2007) Carbon emissions altered Arctic climate forcing. Nature 317:1381–1384

    Google Scholar 

  • McConnell JR, Lamorey GW, Lambert SW, Taylor KC (2002) Continuous ice-core chemical analysis using Inductively Coupled Plasma Mass Spectrometry. Environ Sci Technol 36(1):7–11

    Article  CAS  Google Scholar 

  • More C (2000) Understanding the industrial revolution. Routledge, London

    Google Scholar 

  • Norris R, Arkin W (1998) Known nuclear tests worldwide 1945–98. Bull At Sci 1998:65–67

    Google Scholar 

  • Nriagu JO (1989) A global assessment of natural sources of atmospheric trace metals. Nature 338:47–49

    Article  CAS  Google Scholar 

  • OECD (1992) Uranium resources, production and demand. OECD/NEA-IAEA Editions, Paris

    Google Scholar 

  • Osterberg EC, Handley MJ, Sneed SB, Mayewski PA, Kreutz KJ (2006) Continuous ice core melter system with discrete sampling for major ion, trace element and stable isotopes analysis. Environ Sci Technol 40(10):3355–3361

    Article  CAS  Google Scholar 

  • Pacyna JM, Breivik K, Munch J, Fudala J (2003) European atmospheric emissions of selected organic pollutants, 1970–1995. Atmos Environ 37(1):119–131

    Article  Google Scholar 

  • Paul F, Kääb A, Maisch M, Kellenberger TW, Haeberli W (2004) Rapid disintegration of Alpine glaciers observed with satellite data. Geophy Res Lett 31:L21402. doi:10.1029/2004GL020816

    Article  Google Scholar 

  • Renberg I, Wik-Persson M, Emteryd O (1994) Pre-industrial atmospheric lead contamination detected in Swedish lake sediments. Nature 368:323–326

    Article  CAS  Google Scholar 

  • Rosman KJR, Ly C, Van De Velde K, Boutron CF (2000) A two century record of Pb isotopes in high altitude Alpine snow and ice. Earth Planet Sci Lett 176:413–424

    Article  CAS  Google Scholar 

  • Schotterer U, Oeschger H, Wagenbach D, Münnich K (1985) Information on paleo-precipitation on an high altitude glacier Monte Rosa, Switzerland. Z Gletsch kd Glazialgeol 21(85):379–388

    Google Scholar 

  • Schwikowski M (2004) Reconstruction of European air pollution from Alpine ice cores. In: DeWayne CL, Green JR, Thompson LG (eds) Earth paleoenvironments: records preserved in mid- and low-latitude glaciers. Springer, New York, pp 95–119

    Chapter  Google Scholar 

  • Schwikowski M, Rufibach B, Schwerzmann A, Stampfli D, Barbante C, Planchon F, Gabrielli P, Boutron C (2003) Two new ice cores from Colle Gnifetti, Swiss/Italian Alps. PSI Annual Report 28

  • Schwikowski M, Barbante C, Doering T, Gäggeler HW, Boutron C, Schotterer U, Tobler L, Van De Velde KV, Ferrari C, Cozzi G, Rosman K, Cescon P (2004) Post 17-century changes of European lead emissions recorded in high-altitude alpine snow and ice. Environ Sci Technol 38(4):957–964

    Article  CAS  Google Scholar 

  • Shotyk W (2002) The chronology of anthropogenic, atmospheric Pb deposition recorded by peat cores in three minerogenic peat deposits from Switzerland. Sci Total Environ 292:19–31

    Article  CAS  Google Scholar 

  • Shotyk W, Weiss D, Appleby PG, Cheburkin AK, Frei R, Gloor M, Kramers JD, Reese S, Van Der Knaap WO (1998) History of atmospheric lead deposition since 12370 14C yr BP from a peat bog, Jura Mountains, Switzerland. Science 282:1635–1640

    Article  Google Scholar 

  • Shotyk W, Blaser P, Grunig A, Cheburkin AK (2000) A new approach for quantifying cumulative, anthropogenic, atmospheric lead deposition using peat cores from bogs: Pb in eight Swiss peat bog profiles. Sci Total Environ 249:281–295

    Article  CAS  Google Scholar 

  • Shotyk W, Krachler M, Martinez-Cortizas A, Cheburkin AK, Emons H (2002) A peat bog record of natural, pre-anthropogenic enrichments of trace elements in atmospheric aerosol since 12370 14C yr BP, and their variation with Holocene climate change. Earth Planet Sci Lett 199:21–37

    Article  CAS  Google Scholar 

  • Sigl M, Jenk TM, Kellerhals T, Szidat S, Gaggler HW, Wachler L, Synal H-A, Boutron C, Gabrieli J, Barbante C, Schwikoski M (2009) Towards radiocarbon dating of ice cores. J Glaciol 55(194):985–996

    Article  CAS  Google Scholar 

  • Suter S, Laternser M, Haeberli W, Frauenfelder R, Hoelzle M (2001) Cold firn and ice of high altitude glaciers in the Alps: measurements and distribution modelling. J Glaciol 47(156):85–96

    Article  Google Scholar 

  • Szidat S, Jenk TM, Synal H-A, Kalberer M, Wacker L, Hajdas I, Kasper-Giebl A, Baltensperger U (2006) Contributions of fossil fuel, biomass burning, and biogenic emissions to carbonaceous aerosols in Zurich as traced by 14C. J Geophys Res 111:D07206

    Google Scholar 

  • Vallelonga P, Gabrielli P, Rosman K, Barbante C, Boutron CF (2005) A 220 ky record of Pb isotopes at Dome C Antarctica from analyses of the EPICA ice core. Geophys Res Lett 32. doi:10.1016/j.quascirev.2009.06.019

  • Van De Velde K, Ferrari C, Barbante C, Moret I, Bellomi T, Hong S, Boutron C (1999) A 200 year record of atmospheric cobalt, chromium, molybdenum, and antimony in high altitude alpine firn and ice. Environ Sci Technol 33(20):3495–3501

    Article  Google Scholar 

  • Venkataraman C, Friedlander SK (1994) Size distribution of polycyclic aromatic hydrocarbons and elemental carbon. 2. Ambient measurements and effects of atmospheric processes. Environ Sci Technol 28:563–572

    Article  CAS  Google Scholar 

  • Wagenbach D (1992) Results from the Colle Gnifetti ice-core program, Report of the ESF/EPC Workshop (Greenhouse gases isotopes and trace elements in glaciers as climate evidence of the Holocene). Technical report, Versuchsanstalt für Wasserbau, Hydrologie und Glaziologie, ETH Zürich

  • Wedepohl KH (1995) The composition of the continental crust. Geochim Cosmochim Ac 59:1217–1232

    Article  CAS  Google Scholar 

  • Wolff EW, Fischer H, Fundel F, Ruth U, Twarloh B, Littot GC, Mulvaney R, Rothlisberger R, De Angelis M, Boutron CF, Hansson M, Jonsell U, Hutterli MA, Lambert F, Kaufmann P, Stauffer B, Stocker TF, Steffensen JP, Bigler M, Siggaard-Andersen ML, Udisti R, Becagli S, Castellano E, Severi M, Wagenbach D, Barbante C, Gabrielli P, Gaspari V (2006) Southern Ocean sea-ice extent, productivity and iron flux over the past eight glacial cycles. Nature 440:491–496

    Google Scholar 

  • Yunker MB, Macdonald RW, Vingarzan R, Mitchell RH, Goyette D, Sylvestre S (2002) PAHs in the Fraser River Basin: a critical appraisal of PAH ratio as indicators of PAHs source and composition. Org Geochem 33:489–515

    Article  CAS  Google Scholar 

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  1. Carlo Barbante

    Present address: Accademia Nazionale dei Lincei, Centro B. Segre, via della Lungara 10, 00196, Rome, Italy

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  1. National Research Council, Institute for the Dynamics of the Environmental Processes (CNR-IDPA), Dorsoduro 2137, 30123, Venice, Italy

    Jacopo Gabrieli & Carlo Barbante

  2. Department of Environmental Sciences, Informatics and Statistics, University Ca’ Foscari of Venice, Dorsoduro 2137, 30123, Venice, Italy

    Carlo Barbante

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  1. Jacopo Gabrieli
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Gabrieli, J., Barbante, C. The Alps in the age of the Anthropocene: the impact of human activities on the cryosphere recorded in the Colle Gnifetti glacier. Rend. Fis. Acc. Lincei 25, 71–83 (2014). https://doi.org/10.1007/s12210-014-0292-2

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